Until now, it was commonly thought that colliding molecules get the shakes as the result of energy transfer solely from the smashing of the molecules, but some new research adds a second means by which colliding molecules become vibrationally excited--it is being called the "Tug o' War Mechanism."
The new experiment, transforming the textbook story, was performed in the lab of Richard Zare, chair of the Department of Chemistry at Stanford University. This work on energy transferring, or inelastic, collisions is featured in the July 3, 2008 issue of the journal Nature.